SnIV complexes of N-confused porphyrins and oxoporphyrins--unique fluorescence "switch-on" halide receptors.
SnIV complexes of N-confused porphyrins and oxoporphyrins--unique fluorescence "switch-on" halide receptors.
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DOI：
10.1002/anie.200602481
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发表时间：
2006-10
影响因子：
--
通讯作者：
Yongshu Xie;Tatsuki Morimoto;H. Furuta
中科院分区：
文献类型：
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作者：
Yongshu Xie;Tatsuki Morimoto;H. Furuta
困惑，但不是茫然：与正常卟啉的Sn IV配合物完全相反，N-混乱氧代卟啉的Sn IV配合物可以在轴向位置强烈地结合卤化物，具有显著的荧光增强（参见方案; Ar= Ph，p-CF 3C 6 H4，p-CH 3C 6 H4），因此可以被视为荧光卤化物传感器的新型原型。（化学方程式）
Confused, but not dazed: Totally in contrast to Sn IV complexes of normal porphyrins, Sn IV complexes of N-confused oxoporphyrins can strongly bind halides at the axial position with pronounced fluorescence enhancement (see scheme; Ar= Ph, p-CF 3 C 6 H 4, p-CH 3 C 6 H 4) and can thus be regarded as a novel prototype of fluorescence halide sensors.(Chemical Equation Presented)