Lithium isotope compositions of chondrules, CAI and a dark inclusion from Allende and ordinary chondrites

Lithium isotope compositions of chondrules, CAI and a dark inclusion from Allende and ordinary chondrites
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球粒、CAI 以及阿连德和普通球粒陨石的暗包裹体的锂同位素组成

DOI:
10.1016/j.epsl.2012.02.015
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发表时间:
2012
影响因子:
5.3
通讯作者:
Ott U.
Ott U.
中科院分区:
地球科学1区
文献类型:
--
作者:
Seitz H.-M;Brey G.P;Zipfel J;Ott U.

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块状碳质球粒陨石和普通球粒陨石具有不同的Li同位素组成,表明太阳系早期存在局部储集层和不同的形成条件。这些差异也可能记录在构成球粒陨石的成分中。本文报道了来自Allende(CV3)陨石的89个球粒陨石、10个CaI和1个暗包裹体(DI)以及5个低岩石学类型的普通球粒陨石的Li含量和Li同位素组成。一般来说,球粒陨石的Li同位素组成变化很大,从δ7Li的−8.5Li到+10‰不等,因此从单个球粒陨石中分离出来的球粒陨石的平均同位素组成略轻于其整体。然而,值得注意的是,块状球粒陨石和球粒陨石中锂的含量存在差异。在这里研究的整个球粒陨石中,98%的球粒陨石的Li丰度(在0.20-0.75μg/g范围内)明显低于它们的宿主(通常在1.5μg/g左右)。我们的结果表明,在球粒陨石的形成过程中,没有发生广泛的Li元素和同位素分馏。Li丰度低,但变化大,Li同位素变化范围大,表明球粒形成储集层中存在小规模的非均质性。对于李来说,这种非软骨病的储集层是所有球粒陨石所独有的。块状碳质球粒陨石和普通球粒陨石的锂同位素组成差异(Seitz等人,2007年)很可能是球粒陨石、CaI和基质按不同比例混合的结果。
Bulk carbonaceous and ordinary chondrites have distinct Li isotope compositions, indicating the existence of local reservoirs and distinct formation conditions in the early solar system. These differences may be also recorded in the components that compose chondrites. Here, Li concentrations and Li isotope compositions of 89 chondrules, 10 CAI and 1 dark inclusion (DI) from the Allende (CV3) meteorite and from 5 ordinary chondrites of low petrologic types Semarkona, Bishunpur, Saratov, Bjurböle and Bremervörde are presented. In general, chondrules have highly variable Li isotope compositions, ranging from δ7Li of −8.5 to +10‰, whereby the mean isotope composition of chondrules separated from a single chondrite is slightly lighter than its bulk. Remarkable, however, are the differences in Li concentrations between bulk chondrite and chondrules. Of the entire set studied here, 98% of the chondrules have significantly lower Li abundances (in the range of 0.2 to 0.75μg/g) than their hosts (typically around 1.5μg/g). Our results indicate that Li elemental and isotopic fractionation has not occurred extensively during chondrule formation. Low, but highly variable Li abundances as well as the relatively large range in Li isotopes point to small-scale heterogeneities in the chondrule-forming reservoir. With respect to Li, such a non-chondritic reservoir is unique to all chondrules. The compositional differences in Li isotopes between bulk carbonaceous and ordinary chondrites (Seitz et al., 2007) are likely to be the result of mixing chondrules, CAI and matrix in different proportions.
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发表时间: 2005-01-01
影响因子: 2.2
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通讯作者: Brearley, AJ
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