Evaluation of atmospheric sources of PCDD/Fs, PCBs and PBDEs around a steel industrial complex in northeast China using passive air samplers
Evaluation of atmospheric sources of PCDD/Fs, PCBs and PBDEs around a steel industrial complex in northeast China using passive air samplers
复制标题
使用被动空气采样器评估中国东北钢铁工业园区周围的 PCDD/Fs、PCBs 和 PBDEs 大气来源
DOI：
10.1016/j.chemosphere.2011.06.004
复制
发表时间：
2011-08-01
期刊：
影响因子：
8.8
通讯作者：
Wei, Fusheng
中科院分区：
文献类型：
--
作者：
Li, Xiaomin;Li, Yingming;Wei, Fusheng
过去几十年来，人们对钢铁工业园区排放的多氯二苯并对二恶英和二苯并呋喃（PCDD/Fs）、多氯联苯（PCBs）和多溴二苯醚（PBDEs）的关注有所增加。本研究在鞍山某大型钢铁工业园区内及周边采集了聚亚安酯泡沫塑料（PUF）基被动空气样本。2008年6月至2009年3月在东北工作。调查了钢铁工业园区周围大气中PCDD/Fs、PCBs和PBDEs的含量、季节变化和潜在来源，并评估了钢铁生产中这三种持久性有机污染物（POPs）的潜在贡献。Sigma(17)PCDD/Fs空气浓度(夏季：0.02 ~ 2.77 pg m(-3)；冬季：0.20-9.79 pg m(-3))。Sigma(19) pcb(夏季：23.5-155.8 pg m(-3)；冬季14.6-81.3 pg m(-3))和Sigma(13)PBDEs(夏季2.91-10.7 pg m（-3)，冬季1.10-3.89 pg m(-3)）与其他研究相比相对较低，说明钢铁工业活动并未对该地区环境空气造成严重污染。总体上，冬季PCDD/Fs浓度高于夏季，而多氯联苯和多溴二苯醚浓度呈相反趋势。主成分分析结果表明，燃煤可能是该区PCDD/F的主要来源。(C) 2011 Elsevier Ltd.版权所有。
The concern about emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs) from steel industrial parks has increased in the past decades. In this study, polyurethane foam (PUF)-disk based passive air samples were collected in and around a big steel industrial park of Anshan. Northeast China from June 2008 to March 2009. The levels, seasonal variations and potential sources of PCDD/Fs, PCBs and PBDEs in the atmosphere around the steel industrial complex were investigated, and potential contribution of these three groups of persistent organic pollutants (POPs) from iron and steel production was also assessed. The air concentrations of Sigma(17)PCDD/Fs (summer: 0.02-2.77 pg m(-3); winter: 0.20-9.79 pg m(-3)). Sigma(19)PCBs (summer: 23.5-155.8 pg m(-3); winter: 14.6-81.3 pg m(-3)) and Sigma(13)PBDEs (summer: 2.91-10.7 pg m(-3): winter: 1.10-3.89 pg m(-3)) in this targeted industrial park were relatively low in comparison to other studies, which implied that the industrial activities of iron and steel had not resulted in serious contamination to the ambient air in this area. On the whole, the air concentrations of PCDD/Fs in winter were higher than those of summer, whereas the concentrations of PCBs and PBDEs showed opposite trends. The result from principal component analysis indicated that coal combustion might be the main contributor of PCDD/F sources in this area. (C) 2011 Elsevier Ltd. All rights reserved.