6,6′-Bis-substituted BINOL boronic acids as enantio selective and chemoselective fluorescent chemosensors for D-sorbitol
6,6′-Bis-substituted BINOL boronic acids as enantio selective and chemoselective fluorescent chemosensors for D-sorbitol
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DOI：
10.1016/j.tet.2007.11.061
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发表时间：
2008-02-11
期刊：
影响因子：
2.1
通讯作者：
Zhao, Jianzhang
中科院分区：
文献类型：
--
作者：
Liang, Xiaofen;James, Tony D.;Zhao, Jianzhang
合成了一种新的手性荧光化合物BINOL硼酸1。1的手性识别性质与BINOL硼酸c有很大的不同。传感器1显示出改善的对映选择性以及对糖醇如D-山梨糖醇和D-甘露糖醇的化学选择性。传感器1对D-山梨醇的对映选择性（K-R/K-S）为1：35（pH 9.0），对D-山梨醇/D-甘露醇的化学选择性为20：1。(c)2007爱思唯尔有限公司保留所有权利。
A new chiral fluorescent BINOL boronic acid 1 has been synthesized. The chiral recognition properties of 1 are drastically different from BINOL boronic acid c. Sensor 1 shows improved enantioselectivity as well as chemoselectivity toward sugar alcohols, such as D-sorbitol and D-mannitol. The enantioselectivity of sensor 1 toward D-sorbitol (K-R/K-S) is 1:35 (pH 9.0), and the chemoselectivity for D-sorbitol/D-mannitol is 20:1. (c) 2007 Elsevier Ltd. All rights reserved.