Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines
Rhodium-catalyzed Electrophilic Amination of Arylboronic Acids with Secondary Hydroxylamines
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DOI：
10.1246/cl.161158
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发表时间：
2017-01
影响因子：
1.6
通讯作者：
Tomohiro Yasuhisa;K. Hirano;M. Miura
中科院分区：
文献类型：
--
作者：
Tomohiro Yasuhisa;K. Hirano;M. Miura
本文报道了一种Rh(III)催化的芳基硼酸与仲羟胺的亲电胺化反应。该催化剂与杂芳基硼酸以及O-酰基羟胺氮上的酰基和烷氧基保护基相容，并以较好的产率获得了相应的仲苯胺。
A rhodium(III)-catalyzed electrophilic amination of arylboronic acids with secondary hydroxylamines has been developed. The rhodium catalysis is compatible with heteroarylboronic acids as well as acyl and alkoxycarbonyl protecting groups on the nitrogen of O-acylhydroxylamines, and the corresponding secondary anilines are obtained in good to excellent yields.