Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers.
Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers.
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DOI：
10.1021/ol0505151
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发表时间：
2005-05
期刊：
影响因子：
5.2
通讯作者：
C. Nasveschuk;T. Rovis
中科院分区：
文献类型：
--
作者：
C. Nasveschuk;T. Rovis
[反应：见正文]。采用铝和铜刘易斯酸以中等至良好的产率实现烯丙基乙烯基醚的区域选择性[1，3]重排。三取代烯烃的使用导致Claisen产物的水平降低。
[reaction: see text]. Aluminum and copper Lewis acids were implemented to effect a regioselective [1,3] rearrangement of allylvinyl ethers in moderate to good yields. The use of trisubstituted alkenes leads to depressed levels of Claisen products.