In Situ Photoelectrocatalytic Degradation Behavior of Methylene Blue on Nano- TiO2 Modified Electrode
In Situ Photoelectrocatalytic Degradation Behavior of Methylene Blue on Nano- TiO2 Modified Electrode
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DOI:
10.1149/1.2961056
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发表时间:
2008-10
影响因子:
3.9
通讯作者:
B. Su;Yongjun Ma;Yongling Du;Chaosi Yang;Chunming Wang
中科院分区:
文献类型:
--
作者:
B. Su;Yongjun Ma;Yongling Du;Chaosi Yang;Chunming Wang
The investigation of in situ photoelectrocatalytic degradation of the methylene blue (MB) molecules merged into a nano-TiO 2 modified film by electrochemical techniques is proposed. The methylene blue-Nafion-TiO 2 (MB/Nf/TiO 2 ) modified platinum electrode shows a reversible and faster electron-transfer efficiency in photoelectrocatalytic degradation reactions of surrounding compounds adsorbed on photocatalyst. Open-circuit potential (Eye) of the MB/Nf/TiO 2 electrode shows that the MB molecules have an assured effect with transferred photogenerated electrons on the Nf/TiO 2 interface under UV illumination. A linear regression equation is obtained by the cyclic voltammetry peak current of the residual MB and the reaction time in the degradation process, in which MB undergoes demethylation and C=N bond breaking.