A tetranuclear 3d-4f single molecule magnet:: [CuIILTbIII(hfac)2]2
A tetranuclear 3d-4f single molecule magnet:: [CuIILTbIII(hfac)2]2
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DOI：
10.1021/ja037365e
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发表时间：
2004-01-21
影响因子：
15
通讯作者：
Mrozinski, J
中科院分区：
文献类型：
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作者：
Osa, S;Kido, T;Mrozinski, J
我们现在报告了第一个由 d−f 元素组成的单分子磁体 (SMM)。目前的研究表明，d−f 多核分子的合成是一种非常有前途的 SMM 方法。 (1)d−f多核分子可以通过d-组分和f-组分的组装反应容易地合成，(2)可以通过比d络合物更少数量的金属离子产生高自旋基态，(3)分子磁各向异性很容易从f-组分导出。
We report now the first single molecule magnet (SMM) consisting of d−f elements. The present study demonstrates that the synthesis of the d−f polynuclear molecule is a very promising approach to SMMs. (1) The d−f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.