Metal nitrides, the Mars-van Krevelen mechanism and heterogeneously catalysed ammonia synthesis
Metal nitrides, the Mars-van Krevelen mechanism and heterogeneously catalysed ammonia synthesis
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DOI：
10.1016/j.cattod.2022.08.016
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发表时间：
2023-08-10
期刊：
影响因子：
5.3
通讯作者：
Hargreaves, J. S. J.
中科院分区：
文献类型：
--
作者：
Daisley, A.;Hargreaves, J. S. J.
虽然Mars-van Krevelen机理对于金属氧化物催化的氧化反应已经很好地建立，但是在由金属氮化物催化的氮基反应的情况下研究得少得多。在这篇综述中，一些最近的文献有关的可能的操作的火星-货车Krevelen机制的氨合成金属氮化物催化的，沿着与一些文献有关的氨合成通过化学循环的方法。
Whilst the Mars-van Krevelen mechanism is well established for metal oxide catalysed oxidation reactions, it has been much less studied in the case of nitrogen based reactions catalysed by metal nitrides. In this overview, some of the recent literature in relation to the possible operation of the Mars- van Krevelen mechanism for ammonia synthesis catalysed by metal nitrides is presented, along with some of the literature relating to the synthesis of ammonia via chemical looping approaches.