Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes
Combining Gold and Photoredox Catalysis: Visible Light-Mediated Oxy- and Aminoarylation of Alkenes
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DOI：
10.1021/ja400311h
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发表时间：
2013-04-17
影响因子：
15
通讯作者：
Glorius, Frank
中科院分区：
文献类型：
--
作者：
Sahoo, Basudev;Hopkinson, Matthew N.;Glorius, Frank
使用新型金和光氧化还原双催化系统开发了烯烃与芳基重氮盐的室温分子内氧芳基化和氨基芳基化。首次建立了这两种催化模式的兼容性，并证明了该系统作为扩大碳-碳多重键亲核加成反应范围的方法的潜力。
A room-temperature intramolecular oxy- and aminoarylation of alkenes with aryldiazonium salts has been developed using a novel gold and photoredox dual-catalytic system. The compatibility of these two catalytic modes has been established for the first time and demonstrates the potential of this system as a method to expand the scope of nucleophilic addition reactions to carbon-carbon multiple bonds.