HYDRATION OF ALKALI IONS IN GAS PHASE - ENTHALPIES AND ENTROPIES OF REACTIONS M+(H2O)N-1+H2O = M+(H2O)N
HYDRATION OF ALKALI IONS IN GAS PHASE - ENTHALPIES AND ENTROPIES OF REACTIONS M+(H2O)N-1+H2O = M+(H2O)N
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DOI：
10.1021/j100702a013
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发表时间：
1970-01-01
影响因子：
--
通讯作者：
KEBARLE, P
中科院分区：
文献类型：
--
作者：
DZIDIC, I;KEBARLE, P
导言在过去几年发表的一系列论文1--6中，我们试图证明，有关离子溶剂化的重要信息可以通过测量涉及气体离子和给定“溶剂”蒸气的分子的反应平衡来获得。这种平衡的一个例子是该方法所依赖的碱性离子周围的水分子的聚集
Introduction In a series of papers published over the past few years1--6 we have tried to show that important informa-tion on the solvation of ions can be obtained by mea-surement of reaction equilibria involving gaseous ions and molecules of a given “solvent” vapor. An example of such an equilibrium is the clustering of water mol-ecules around an alkali ion+ The method relies on