Occurrence and distribution of organophosphate flame retardants (OPFRs) in soil and outdoor settled dust from a multi-waste recycling area in China

Occurrence and distribution of organophosphate flame retardants (OPFRs) in soil and outdoor settled dust from a multi-waste recycling area in China
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中国多废物回收区土壤和室外沉降灰尘中有机磷酸酯阻燃剂 (OPFR) 的存在和分布

DOI:
10.1016/j.scitotenv.2018.01.013
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发表时间:
2018-06-01
影响因子:
9.8
通讯作者:
Kannan, Kurunthachalam
Kannan, Kurunthachalam
中科院分区:
环境科学与生态学1区
文献类型:
--
作者:
Wang, Yu;Sun, Hongwen;Kannan, Kurunthachalam

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采用开放式(ORS)和半封闭回收(SCRS)两种不同的回收方式,对某多废弃物(电子、塑料和橡胶废弃物以及废弃的家用电器和车辆)回收区收集的土壤和室外沉降尘样品中12种有机磷阻燃剂(OPFRs)的分布进行了测定。在分析的12个opfr中,11个在所有土壤和粉尘样品中检测频率为75%-100%。土壤样品中的Sigma OPFR浓度在ORS (122-2100 ng/g)显著高于SCRS (58.5-316 ng/g)和附近农田(37.7-156 ng/g)。沙尘样品中Sigma OPFR浓度高于土壤样品,其空间分布与土壤相似,从ORS (1390 ~ 42700 ng/g)降至SCRS (914 ~ 7940 ng/g)。三(2-氯异丙基)磷酸(TCIPP)是两种土壤(
Distribution of 12 organophosphate flame retardants (OPFRs) was determined in soil and outdoor settled dust samples collected from a multi-waste (electronic, plastic, and rubber wastes and abandoned household appliances and vehicles) recycling area, that encompassed different modes of operation i.e. open (ORS) and semi-closed recycling (SCRS). Among the twelve OPFRs analyzed, eleven were detected at a frequency of 75%-100% in all soil and dust samples. In soil samples, Sigma OPFR concentrations were significantly higher at ORS (122-2100 ng/g) than at SCRS (58.5-316 ng/g) and nearby farmlands (37.7-156 ng/g). The Sigma OPFR concentrations in dust samples were higher than those in soil samples with spatial distribution similar to that observed for soil, decreasing from ORS (1390-42,700 ng/g) to SCRS (914-7940 ng/g).Tris(2-chloroisopropyl) phosphate (TCIPP) was the major OPFRs in both soil (