A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device
A radiation sensitive hybrid polymer based on an Mn-Anderson polyoxometalate cluster and a UV active organic monomer: synergistic effects lead to improved photocurrent in a photoresponse device
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DOI：
10.1039/c5ra05550d
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发表时间：
2015-04
期刊：
影响因子：
3.9
通讯作者：
Vishwanath S. Kalyani;V. Satyanarayana;Abdus Salam Sarkar;Ashwani Kumar;S. Pal;S. Ghosh;K. Gonsalves-K.-Gonsa
中科院分区：
文献类型：
--
作者：
Vishwanath S. Kalyani;V. Satyanarayana;Abdus Salam Sarkar;Ashwani Kumar;S. Pal;S. Ghosh;K. Gonsalves-K.-Gonsa
以Mn-Anderson簇基杂化物和UV活性有机单体为原料合成了一种新的辐射敏感型多金属氧酸盐/聚合物杂化物POM-MAPDST，并通过制作ITO/ POM-MAPDST /Al器件测试了其光响应性能。该器件在光照下表现出改善的I-V特性，这可能是由于多金属酸氧簇与杂化聚合物的有机组分之间的协同相互作用。
A new radiation sensitive polyoxometalate/polymer hybrid, POM–MAPDST, has been synthesized from an Mn-Anderson cluster based hybrid and a UV active organic monomer and tested for its photo-response properties by fabricating an ITO/POM–MAPDST/Al device. This device showed improved I–V characteristics under illumination possibly due to the synergistic interactions between the polyoxometalate cluster and the organic components of the hybrid polymer.