Stoichiometric aerobic PtII-Me bond cleavage in aqueous solutions to produce methanol and a PtII(OH) complex.
Stoichiometric aerobic PtII-Me bond cleavage in aqueous solutions to produce methanol and a PtII(OH) complex.
复制标题
水溶液中化学计量需氧 PtII-Me 键断裂产生甲醇和 PtII(OH) 络合物。
DOI:
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发表时间:
2006
影响因子:
15
通讯作者:
J. Khusnutdinova
中科院分区:
文献类型:
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作者:
A. N. Vedernikov;Seth A Binfield;P. Zavalij;J. Khusnutdinova
Di(2-pyridyl)methanesulfonate ligand allows for facile aerobic oxidation of a PtIIMe complex into PtIVMe(OH)2 species and clean C-O reductive elimination of methanol from the latter in either acidic or basic aqueous solutions.