Photooxidation of matrix-isolated iron pentacarbonyl. II: Binary iron oxide reaction products and the overall reaction mechanism
Photooxidation of matrix-isolated iron pentacarbonyl. II: Binary iron oxide reaction products and the overall reaction mechanism
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基质隔离的五羰基铁的光氧化。
DOI：
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发表时间：
1992
期刊：
影响因子：
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通讯作者：
M. Almond
中科院分区：
文献类型：
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作者：
Michael Fanfarillo;A. J. Downs;T. M. Greene;M. Almond
二元氧化铁分子F和G与CO和CO2一起通过长时间的紫外光分解（λ=ca. 312 nm）的Fe（CO）5分子分离的O2掺杂的氩矩阵在约.两万通过分析富18 O分子在800-1000 cm-1区域内红外吸收的数目、能量和相对强度，确定了每种氧化物的身份和可能的结构
Binary iron oxide molecules F and G are generated, together with CO and CO 2 , by prolonged UV photolysis (λ=ca. 312 nm) of Fe(CO) 5 molecules isolated in O 2 -doped argon matrices at ca. 20 K. The identity and likely structure of each of the oxides have been established by analyzing the number, energies, and relative intensitia of the IR absorptions displayed by the 18 O-enriched molecule in the region 800-1000 cm -1