Roles of supermolecule structure of melamine phosphomolybdate in intumescent flame retardant polypropylene composites

Roles of supermolecule structure of melamine phosphomolybdate in intumescent flame retardant polypropylene composites
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三聚氰胺磷钼酸盐超分子结构在膨胀型阻燃聚丙烯复合材料中的作用

DOI:
10.1016/j.jaap.2016.03.007
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发表时间:
2016-05-01
影响因子:
6
通讯作者:
Ding, Peng
Ding, Peng
中科院分区:
化学2区
文献类型:
--
作者:
Wang, Chengle;Li, Juan;Ding, Peng

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In this paper, supermolecular structure of melamine phosphomolybdate (MAPMo) was tailored by changing the ratio of MA/PMo. Effects of MAPMo on flame retardant efficiency of polypropylene/intumescent flame retardant (PP/IFR) system were investigated by using limiting oxygen index (LOI), UL-94 testing, microscale combustion calorimetry (MCC) etc. The thermal degradation behaviors of PP composites were tested by thermal gravimetric analysis (TGA). The results showed that the formation of supermolecular increases the thermal stability of MA and the ratio of MA/PMo has great effect on flame retardancy of PP/IFR. With the addition of 15.5 wt% IFR and 0.5 wt% MAPMo (MA/PMo