Group 10 transition-metal complexes with metal-silicon bonds derived from 1,2-disilylbenzenes and bis(2-silylphenyl)silane
Group 10 transition-metal complexes with metal-silicon bonds derived from 1,2-disilylbenzenes and bis(2-silylphenyl)silane
复制标题
DOI：
10.1016/j.ccr.2005.12.010
复制
发表时间：
2006-05
影响因子：
20.6
通讯作者：
S. Shimada;Masato Tanaka
中科院分区：
文献类型：
--
作者：
S. Shimada;Masato Tanaka
本文介绍了氢硅烷与10族过渡金属配合物反应形成的具有金属硅键的10族过渡金属配合物，重点介绍了1,2-二苯基苯、1-二甲基硅基-2-硅基苯和双（2-硅苯基）硅烷的独特化学性质。这些氢硅烷提供了空间上较少拥挤的双齿和三齿硅基配体，并使得稳定一些不寻常的单核、二核和三核聚（硅基）基团10金属配合物成为可能，包括那些高形式价态的金属配合物。
This article provides an account of the group 10 transition-metal complexes with metal–silicon bonds formed by the reaction of hydrosilanes with group 10 transition-metal complexes, with particular emphasis on the unique chemistry of 1,2-disilylbenzene, 1-dimethylsilyl-2-silylbenzene and bis(2-silylphenyl)silane. These hydrosilanes provide sterically less congested bidentate and tridentate silyl ligands and make it possible to stabilize a number of unusual mono-, di- and trinuclear poly(silyl) group 10 metal complexes including those of high formal valence state.