Alkenyl succinic anhydride (ASA)
Alkenyl succinic anhydride (ASA)
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DOI：
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发表时间：
2005
期刊：
影响因子：
0.6
通讯作者：
J. M. Gess;D. S. Rende
中科院分区：
文献类型：
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作者：
J. M. Gess;D. S. Rende
在20世纪60年代，将烯基琥珀酸酐（阿萨）加入到将使纤维素纤维在中性/碱性条件下（在pH 7.5-8.5的范围内）对水的吸附的抗性增加0. Wurzburg和E.国家淀粉和化学公司的Mazzerella [1]。阿萨的钠盐可以与明矾以类似于树脂酸的方式络合以在酸性造纸中施胶。此外，商业阿萨产品还用于pH 4.5-6.5的酸性造纸，用于制造回收挂面纸板、高级纸、屋顶和模塑产品。阿萨的发展为造纸商提供了AKD（烷基烯酮二聚体）的替代品，AKD是由C。赫拉克勒斯化学公司的Weissgerber [2]。两种材料都以阳离子分散体的形式施加到纤维素纤维上，然后将纤维形成网，压制和干燥。这两种施胶剂帮助造纸商从使用粘土作为主要颜料的酸性造纸过渡到使用碳酸钙的中性/碱性造纸。
Alkenyl succinic anhydride (ASA) was added to the agents that would increase the resistance of cellulose fibers to the adsorption of water under neutral/alkaline conditions (at pH's in the range of 7.5-8.5) in the 1960's by 0. Wurzburg and E. Mazzerella of the National Starch and Chemical Company [1]. The sodium salt of ASA can be complexed with alum in a similar manner to resin acids to size in acid papermaking. Furthermore, commercial ASA products are also being used in acid papermaking, pH 4.5-6.5, in the manufacture of recycle linerboard, fine paper, roofing and molded products. The development of ASA gave papermakers an alternative to AKD (alkyl ketene dimer), a product that had been developed by C. Weissgerber of Hercules Chemical Company [2]. Both materials are applied to cellulose fibers in the form of cationic dispersion prior to the fibers being formed into a web, pressed and dried. The two sizing agents have helped papermakers make the transition from acid papermaking using clay as the primary pigment to neutral/alkaline papermaking using calcium carbonate.