Isolation of a stable covalent selenium azide RSeN3.
Isolation of a stable covalent selenium azide RSeN3.
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DOI：
10.1021/ja038975h
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发表时间：
2004-01
影响因子：
15
通讯作者：
T. Klapötke;B. Krumm;K. Polborn
中科院分区：
文献类型：
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作者：
T. Klapötke;B. Krumm;K. Polborn
合成了第一个共价硒叠氮化物2-Me_2NCH_2C_6H_4SeN_3，并对其进行了全面表征，包括晶体结构测定。实验结果表明，RSeN 3的相对稳定性高度依赖于取代基R的配位能力的性质，导致杂环两性离子结构。
The first covalent selenium azide 2-Me2NCH2C6H4SeN3 has been synthesized and fully characterized including crystal structure determination. As shown by the experimental results, the relative stability of RSeN3 highly depends on the nature of the coordinating ability of the substituent R, resulting in a heterocyclic zwitterionic structure.