Design and Synthesis of Concentration Gradient Prussian Blue Analogues
Design and Synthesis of Concentration Gradient Prussian Blue Analogues
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DOI：
10.1021/acs.cgd.0c01271
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发表时间：
2021-01-20
影响因子：
3.8
通讯作者：
Talham, Daniel R.
中科院分区：
文献类型：
--
作者：
Jeon, SuKyung;Li, Carissa H.;Talham, Daniel R.
探索了一种基于不同普鲁士蓝类似物的混合组成粒子的合成路线，这些普鲁士蓝类似物在二价金属或六氰基金属酸盐组分中含有梯度。确定了有利于动态捕获梯度结构的合成条件和成分组合，并将这些条件与成分中较难实现梯度的情况进行了对比。通过对几种组合的探索，PBA组分的相对沉淀速率被证明是实现对梯度合成的控制的关键决定因素，这一参数因PBA家族中不同的结晶机制而变得复杂。对于一个组合，六氰亚铁酸钴和六氰亚铁酸镍，展示了一系列完整的粒子，包括具有不同二价金属离子梯度的粒子，具有梯度壳层的核心粒子，以及由梯度分隔的离散核壳成分的粒子。将梯度异质结的结构特征与单个单相和更标准的核壳粒子进行了比较。
A synthetic route to mixed composition particles based on different Prussian blue analogues containing a gradient in either the divalent metal or the hexacyanometalate components is explored. Synthetic conditions and combinations of components that favor kinetically trapping the gradient structures are identified, and these are contrasted with cases for which gradients in composition are harder to achieve. By an exploration of several combinations, the relative rate of precipitation of the PBA components is shown to be the crucial determinant for achieving control over the gradient synthesis, a parameter that is complicated by differing crystallization mechanisms within the PBA family. For one combination, cobalt hexacyanoferrate with nickel hexacyanoferrate, a complete series of particles is demonstrated, including particles with differing divalent metal ion gradients, core particles with a gradient shell, and particles with discrete core and shell components separated by a gradient. The structural characteristics of the gradient heterostructures are compared to the individual single phases and to more standard core-shell particles.