Positional control of encapsulated atoms inside a fullerene cage by exohedral addition.
Positional control of encapsulated atoms inside a fullerene cage by exohedral addition.
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DOI：
10.1021/ja054346r
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发表时间：
2005-10
影响因子：
15
通讯作者：
M. Yamada;T. Nakahodo;T. Wakahara;T. Tsuchiya;Y. Maeda;T. Akasaka;M. Kako;K. Yoza;E. Horn;
中科院分区：
文献类型：
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作者：
M. Yamada;T. Nakahodo;T. Wakahara;T. Tsuchiya;Y. Maeda;T. Akasaka;M. Kako;K. Yoza;E. Horn;
成功合成了内嵌金属富勒烯的外配位功能化衍生物Ce2@C80（Mes2SiCH2SiMes2），并对其进行了表征。X射线晶体学和NMR光谱分析表明，Ce2@C80中的两个金属原子的自由无规运动是由外配位化学功能化控制的。
The exohedrally functionalized derivative of endohedral metallofullerene, Ce2@C80(Mes2SiCH2SiMes2), was successfully synthesized and fully characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that the free random motion of two metal atoms in Ce2@C80 is controlled inside the cage by exohedral chemical functionalization.