Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)-H Borylation of Methylchlorosilanes
Catalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)-H Borylation of Methylchlorosilanes
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DOI：
10.1021/ja307956w
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发表时间：
2012-10-24
影响因子：
15
通讯作者：
Suginome, Michinori
中科院分区：
文献类型：
--
作者：
Ohmura, Toshimichi;Torigoe, Takeru;Suginome, Michinori
甲基氯硅烷的甲基在铱催化的反应中与双（频哪醇合）二硼在环己烷中在80 ℃下进行C-H硼基化，选择性地得到（硼基甲基）氯硅烷。
A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 degrees C, giving (borylmethyl)chlorosilanes selectively.