Magnetron sputtering in the creation of photonic nanostructures derived from Sasakia Charonda Formosana-butterfly wings for applied in dye-sensitized solar cells

Magnetron sputtering in the creation of photonic nanostructures derived from Sasakia Charonda Formosana-butterfly wings for applied in dye-sensitized solar cells
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磁控溅射创建源自 Sasakia Charonda Formosana 蝴蝶翅膀的光子纳米结构,用于染料敏化太阳能电池

DOI:
10.1016/j.jpowsour.2016.06.060
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发表时间:
2016-09
影响因子:
9.2
通讯作者:
Xu Jinzhang
Xu Jinzhang
中科院分区:
工程技术2区
文献类型:
--
作者:
Niu Haihong;Zhou Ru;Cheng Cong;Zhang Gonghai;Hu Yu;Huang Bin;Zhang Shouwei;Shang Xin;Xia Mei;Xu Jinzhang

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从蝴蝶翅膀上的结构中创造新的功能材料已经引起了人们对各种研究课题的兴趣。然而,需要一种简洁的方法可以导致高质量,精确和方便的过程,用于制造基于蝴蝶翅膀的具有独特功能的复杂纳米结构复制品。在这里,我们开发了一种基于磁控溅射金属Ti工艺的简洁方法,用于生物模板,用于细化分级多孔二氧化钛光子晶体纳米结构(TiO2单键PCN),它们本身来自Sasakia Charonda Formosana(S. Charonda)蝴蝶。首次在P25活性层上沉积了TiO2单键PCN,并将其用于DSSC作为光阳极的光散射层,其功率转换效率高达8.7%。值得注意的是,已经实现了大大增强的光电流密度和突出的光电化学转换能力,这超过了大多数先前报道的光阳极以及类似的基于蝴蝶复制的器件结构。我们的研究提出了许多令人兴奋的机会,开发人工工程蝴蝶翅膀为基础的太阳能到燃料转换。
Creating new functional materials derived from the structures seen on butterfly wings has achieved interest in a variety of research topics. However, there need a concision approach could result in a high-quality, precise, and convenient process for the fabrication of complex nanostructures replication with unique functionalities based on the butterfly wings. Here we developed a pithy approach based on a magnetron sputtering metal Ti process for biotemplating used to refine hierarchically porous titanium dioxide photonic crystal nanostructures (TiO2single bondPCN), themselves derived from nanostructures present on the wings of Sasakia Charonda Formosana (S. Charonda) butterflies. For the first time, the TiO2single bondPCN were deposited on the top of the P25 active layer and were used to fabricate DSSCs as the light-scattering layers of photoanodes with power conversion efficiencies of up to 8.7%. Remarkably, a much enhanced photocurrent density and a prominent photoelectrochemical conversion capability have been achieved, which are exceeding most of the previously reported photoanodes as well as a similar butterflies replication-based device structure. Our study suggests many exciting opportunities of developing artificially engineered butterfly wing-based solar-to-fuel conversion.
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