A tosylimido analogue of a nonheme oxoiron(IV) complex
A tosylimido analogue of a nonheme oxoiron(IV) complex
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DOI：
10.1002/anie.200602799
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发表时间：
2006-01-01
影响因子：
16.6
通讯作者：
Que, Lawrence, Jr.
中科院分区：
文献类型：
--
作者：
Klinker, Eric J.;Jackson, Timothy A.;Que, Lawrence, Jr.
(图所示)高价多功能性：N4Py是一种多功能的五齿配体，证明可以稳定高价氧和亚胺化合物。[Fe IV(NTS)(N_4Py)]~(2+)配合物(见密度泛函优化结构)的光谱性质为：具有一个S=1的铁(IV)中心，其Fe=N键(1.73？)比其氧代类似物的Fe=O键(1.65？)长。
(Figure Presented) High-valent versatility: N4Py is a versatile pentadentate ligand demonstrated to stabilize both high-valent oxo and imido compounds. The [Fe IV (NTs)(N4Py)] 2+ complex (see DFT-optimized structure) has been characterized spectroscopically and formulated as having an S= 1 iron (IV) center with an Fe= N bond (1.73 Å) that is longer than the Fe= O bond of its oxo analogue (1.65 Å).