Membrane reactors : distributing reactants to improve selectivity and yield
Membrane reactors : distributing reactants to improve selectivity and yield
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膜反应器：分配反应物以提高选择性和产率
DOI：
10.1002/9783527629725
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发表时间：
2010
期刊：
影响因子：
--
通讯作者：
A. Seidel
中科院分区：
文献类型：
--
作者：
A. Seidel
前言化学反应工程的基本问题和膜反应器的潜力化学反应工程中的挑战膜反应器的概念膜的选择性问题填充床和膜反应器中的反应速率、转化率、选择性和产率分布配料膜反应器的动力学兼容性膜反应器的现状膜反应器的模型介绍动量、质量和热平衡传递动力学简化模型的可解性、离散化方法和快速求解在FLUENT，MooNMD，COMSOL和PROPT结论模型反应的催化和反应动力学介绍乙烷催化氧化脱氢的反应网络和构效关系动力学模型的推导多孔膜和膜反应器中的传递现象介绍分散对流扩散方程在膜反应器中的速度场传递系数的测定和模型的验证CMR中对流和扩散传递现象的参数分析CMR中对流和扩散传递现象的参数研究填充床膜反应器介绍原理和模型分析乙烷氧化脱氢制乙烯的实验结果沸腾床中丙烷氧化脱氢的实验结果膜反应器简介固体电解质膜反应器介绍固体电解质膜反应器操作和材料方面固体电解质膜反应器应用离子导电材料的建模结论膜反应器的非线性动力学引入化学平衡模式的形成极限结论不同膜反应器的比较不同类型膜反应器的一般情况不同类型膜反应器中乙烷氧化脱氢的一般结论
Preface BASIC PROBLEMS OF CHEMICAL REACTION ENGINEERING AND POTENTIAL OF MEMBRANE REACTORS Challenges in Chemical Reaction Engineering Concepts of Membrane Reactors Available Membranes Illustration of the Selectivity Problem Reaction Rate, Conversion, Selectivity and Yield Distributed Dosing in Packed-Bed and Membrane Reactors Kinetic Compatibility in Membrane Reactors Current Status of Membrane Reactors of the Distributor Type MODELING OF MEMBRANE REACTORS Introduction Momentum, Mass and Heat Balances Transport Kinetics Reduced Models Solvability, Discretization Methods and Fast Solution Implementation in FLUENT, MooNMD, COMSOL and ProMoT Conclusion CATALYSIS AND REACTION KINETICS OF A MODEL REACTION Introduction The Reaction Network of the Oxidative Dehydrogenation of Ethane Catalysts and Structure-Activity Relations Derivation of a Kinetic Model TRANSPORT PHENOMENA IN POROUS MEMBRANES AND MEMBRANE REACTORS Introduction Aspects of Discretizing Convection-Diffusion Equations Velocity Fields in Membrane Reactors Determination of Transport Coefficients and Validation of Models Analysis of Convective and Diffusive Transport Phenomena in a CMR Parametric Study of a CMR Conclusion PACKED-BED MEMBRANE REACTORS Introduction Principles and Modeling Model-Based Analysis of a Distributed Dosing via Membranes Experimental Results for the Oxidative Dehydrogenation of Ethane to Ethylene Results for the Oxidative Dehydrogenation of Propane Summary and Conclusions FLUIDIZED-BED MEMBRANE REACTORS Introduction Modeling of the Distributed Reactant Dosage in Fluidized Beds Experimental Conclusions SOLID ELECTROLYTE MEMBRANE REACTORS Introduction Operational and Material Aspects in Solid Electrolyte Membrane Reactors Modeling of Solid Electrolyte Membrane Reactors Membrane Reactors Applying Ion-Conducting Materials Conclusions NONLINEAR DYNAMICS OF MEMBRANE REACTORS Introduction Limit of Chemical Equilibrium Pattern Formation Conclusions COMPARISON OF DIFFERENT MEMBRANE REACTORS General Aspects Regarding Membrane Reactors of the Distributor Type Oxidative Dehydrogenation of Ethane in Different Types of Membrane Reactors General Conclusion