Direct Synthesis of Dialkylaryl-vinylsilane Derivatives: Metathesis of Dialkylaryl-iso-propenylsilane and Its Application to Tetracyclic Silacycle Dye Synthesis
Direct Synthesis of Dialkylaryl-vinylsilane Derivatives: Metathesis of Dialkylaryl-iso-propenylsilane and Its Application to Tetracyclic Silacycle Dye Synthesis
复制标题
二烷基芳基-乙烯基硅烷衍生物的直接合成：二烷基芳基-异丙烯基硅烷的复分解及其在四环硅环染料合成中的应用
DOI：
10.1039/c9cc06777a
复制
发表时间：
2019
期刊：
影响因子：
--
通讯作者：
Mitsuhiro Arisawa
中科院分区：
文献类型：
--
作者：
Shohei Yoshioka;Tsunayoshi Takehara;Tsuyoshi Matsuzaki;Takeyuki Suzuki;Hirofumi Tsujino;Tadayuki Uno;Yasuo Tsutsumi;Kenichi Murai;Hiromichi Fujioka;Mitsuhiro Arisawa
使用二烷基芳基-异丙烯基硅烷作为底物实现了迄今尚未完成的二烷基芳基乙烯基硅烷的复分解。此外，我们发现钌卡宾络合物和二烷基芳基乙烯基硅烷的复分解困难的原因是碳化物络合物的形成。
The metathesis of dialkylarylvinylsilane, which has not been accomplished to date, is achieved using dialkylaryl-iso-propenylsilane as a substrate. In addition, we discovered that the reason why the metathesis of a ruthenium carbene complex and dialkylarylvinylsilane is difficult is the formation of a carbide complex.