Reductive N−N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp*Fe{N(SiMe3)2}
Reductive N−N Bond Cleavage of Diphenylhydrazine and Azobenzene Induced by Coordinatively Unsaturated Cp*Fe{N(SiMe3)2}
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DOI：
10.1021/om0602963
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发表时间：
2006-05
期刊：
影响因子：
2.8
通讯作者：
Y. Ohki;Yuko Takikawa;T. Hatanaka;K. Tatsumi
中科院分区：
文献类型：
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作者：
Y. Ohki;Yuko Takikawa;T. Hatanaka;K. Tatsumi
配位不饱和铁（II）胺配合物Cp*Fe{N(SiMe3)2}(1)是二苯肼N−N键断裂的有效前体。偶氮苯的NN键也被1激活。
The coordinatively unsaturated iron(II) amido complex Cp*Fe{N(SiMe3)2} (1) serves as an efficient precursor for the cleavage of the N−N bond of diphenylhydrazine. The NN bond of azobenzene was also found to be activated by 1 in the presence of pinacolborane.