On the structure of the Phytophthora α1 mating hormone:: synthesis and comparison of four candidate stereoisomers

On the structure of the Phytophthora α1 mating hormone:: synthesis and comparison of four candidate stereoisomers
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DOI:
10.1016/j.tetlet.2007.09.054
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发表时间:
2007-11-05
影响因子:
1.8
通讯作者:
Curran, Dennis P.
Curran, Dennis P.
中科院分区:
化学4区
文献类型:
--
作者:
Bajpai, Reena;Yang, Fanglong;Curran, Dennis P.

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已经合成了疫霉α 1交配激素的候选结构的两种双化合物混合物。混合物被设计成在C3具有不同的构型,但被证明是相同的。这表明差向异构化发生在C3,与天然样品的数据比较表明这也是异构体的混合物。(c)2007爱思唯尔有限公司保留所有权利。
Two two-compound mixtures of candidate structures for the Phytophthora alpha 1 mating hormone have been synthesized. The mixtures were designed to have differing configurations at C3, but proved to be identical. This suggests that epimerization occurred at C3, and comparison with the data for the natural samples suggest that this is also a mixture of isomers. (c) 2007 Elsevier Ltd. All rights reserved.