Novel poly(p-phenylenevinylene)s with a phenylazomethine dendron as a metal-collecting site.

Novel poly(p-phenylenevinylene)s with a phenylazomethine dendron as a metal-collecting site.
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DOI:
10.1021/ol0497741
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发表时间:
2004-03
期刊:
影响因子:
5.2
通讯作者:
Atsushi Kimoto;Kiriko Masachika;Jun-Sang Cho;M. Higuchi;Kimihisa Yamamoto
Atsushi Kimoto;Kiriko Masachika;Jun-Sang Cho;M. Higuchi;Kimihisa Yamamoto
中科院分区:
化学1区
文献类型:
--
作者:
Atsushi Kimoto;Kiriko Masachika;Jun-Sang Cho;M. Higuchi;Kimihisa Yamamoto

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通过Heck反应,通过稀土金属离子配位填充对苯偶氮亚甲基(DPA)的配位,合成了以树枝状的苯基偶氮亚甲胺(DPA)为金属捕集中心的新型聚对苯乙叉S(PPVS)。
Novel poly(p-phenylenevinylene)s (PPVs) with a dendritic phenylazomethine (DPA) as a metal-collecting site were synthesized via the Heck reaction by filling the coordination site of DPA moiety via complexation with rare earth metal ions.