NiCo2O4@MnMoO4 core-shell flowers for high performance supercapacitors
NiCo2O4@MnMoO4 core-shell flowers for high performance supercapacitors
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用于高性能超级电容器的NiCo2O4@MnMoO4核壳花
DOI:
10.1039/c6ta02746f
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发表时间:
2016-06-07
影响因子:
11.9
通讯作者:
Zhang, Xiaojun
中科院分区:
文献类型:
--
作者:
Gu, Zhengxiang;Zhang, Xiaojun
Hierarchical NiCo2O4@MnMoO4 core-shell nanomateriat on nickel foam was designed via a facile hydrothermal method. A possible growth mechanism of the MnMoO4 is in which the molybdenum acid radical captures part manganese ions of the MnMoO4 nanoflowers. When regarded as binder-free electrodes for supercapacitors (SCs), such special NiCo2O4@MnMoO4 core-shell hybrid electrodes exhibit ultra-high specific capacitances several times larger than a pristine NiCo2O4 electrode. The electrodes possess high specific capacitance of 1118 F g(-1) at a current density of 1 A g(-1) and excellent cycling stability (5000 cycles). This remarkable electrochemical performance is ascribed to the effective combination of two electroactive materials and the rational array configuration.