Environmental benign synthesis of Nano-SSZ-13 via FAU trans-crystallization: Enhanced NH3-SCR performance on Cu-SSZ-13 with nano-size effect
Environmental benign synthesis of Nano-SSZ-13 via FAU trans-crystallization: Enhanced NH3-SCR performance on Cu-SSZ-13 with nano-size effect
复制标题
通过 FAU 转晶法环境无害地合成 Nano-SSZ-13：通过纳米尺寸效应增强 Cu-SSZ-13 的 NH3-SCR 性能
DOI：
10.1016/j.jhazmat.2020.122986
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发表时间：
2020-11-05
影响因子：
13.6
通讯作者：
Liu, Fudong
中科院分区：
文献类型：
--
作者：
Liang, Jian;Mi, Yangyang;Liu, Fudong
Small pore zeolites with chabazite structure have been commercialized for selective catalytic reduction (SCR) of nitrogen oxides (NOx) with ammonium (NH3) from diesel exhaust. However, conventional zeolite synthesis processes detrimental effects on the environment due to the consumption of large amount of water, organic templates. Thus, this study proposed a green synthesis process with addition of minimal amount of water, structure directing agent and shortened steps to prepare nano-sized SSZ-13 (0.12 mu m) using trans-crystallization strategy and exhibited enhanced performance for NOx removal after copper ion-exchange. The operation temperature window (NOx conversion > 90 %) as well as the SO2 and H2O resistance over the green-route prepared nano-sized SSZ-13 (178-480 degrees C) outperformed the conventional SSZ-13 (29.8 mu m, 211-438 degrees C) mainly due to the much shorter diffusion path. This clearly implied that the mass transportation was key for NH3-SCR of NOx on such small pore zeolite catalysts, which was further confirmed via an in-depth mass transportation calculation process. These results demonstrate that the Cu-nano-sized SSZ-13 prepared by the environmental benign route has great potential to act as a new generation of deNO(x) catalyst for diesel exhaust and provided a guideline for researchers to develop new methods to synthesize nano-catalysts for air pollution control.
