STEREOSELECTIVE SYNTHESIS OF 3-(PHENYLSULFONYL)-2,5-DISUBSTITUTED TETRAHYDROFURANS VIA 5-ENDO-TRIG RING-CLOSURE REACTIONS
STEREOSELECTIVE SYNTHESIS OF 3-(PHENYLSULFONYL)-2,5-DISUBSTITUTED TETRAHYDROFURANS VIA 5-ENDO-TRIG RING-CLOSURE REACTIONS
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DOI：
10.1016/s0040-4039(00)92345-1
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发表时间：
1992-01-28
影响因子：
1.8
通讯作者：
SMITH, AM
中科院分区：
文献类型：
--
作者：
CRAIG, D;SMITH, AM
报道了一系列磺酰基取代的高烯丙醇的合成及其5-内位-β-环化反应。 一些竞争反应进行了描述，并提出了一个模型来解释所观察到的立体选择性。
The synthesis and stereoselective 5-endo-trig cyclization reactions of a series of sulphonyl-substituted homoallylic alcohols are reported. Some competing reactions are described, and a model is proposed to account for the observed stereoselectivity.