KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION

KINETICS OF NON-ISOTHERMAL CRYSTALLIZATION
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DOI:
10.1016/0032-3861(71)90041-3
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发表时间:
1971-01-01
期刊:
影响因子:
4.6
通讯作者:
OZAWA, T
OZAWA, T
中科院分区:
化学2区
文献类型:
--
作者:
OZAWA, T

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通过推广Avrami方程,导出了形核和长大过程的非等温动力学。动力学分析的热分析数据的过程中也被描述和应用到DSC曲线的结晶通过冷却聚(对苯二甲酸乙二醇酯)在恒定速率。结晶被认为是通过核随机形成并在三维中生长来进行的。
Non-isothermal kinetics of the process of nucleation and its growth are derived by extending Avrami's equation. Kinetic analysis of the thermoanalytical data of the process is also described and applied to DSC curves of crystallization obtained by cooling poly(ethylene terephthalate) at constant rates. Crystallization is thought to proceed by nuclei being formed randomly and growing in three-dimensions.