Organic synthesis using enzymes in supercritical carbon dioxide
Organic synthesis using enzymes in supercritical carbon dioxide
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DOI：
10.1039/b404564p
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发表时间：
2004-09
期刊：
影响因子：
9.8
通讯作者：
T. Matsuda;T. Harada;Kaoru Nakamura
中科院分区：
文献类型：
--
作者：
T. Matsuda;T. Harada;Kaoru Nakamura
酶已在超临界二氧化碳(ScCO2)中使用，而不是在传统介质中使用，以使酶反应更环保。本文介绍了SCCO_2中的几种酶促不对称合成方法，如脂肪酶的酯化反应、醇脱氢酶的还原反应等。还描述了通过脱羧酶进行的羧化。
Enzymes have been used in supercritical carbon dioxide (scCO2) rather than in the conventional media to make enzyme reactions greener. This review introduces some enzymatic asymmetric synthesis in scCO2 such as esterification by a lipase and reduction by an alcohol dehydrogenase. A carboxylation by a decarboxylase is also described.