Cover Feature: Spectroscopic Identification of Disordered Molecular Cations in Defect Perovskite-Like A Ln (HCO 2 )(C 2 O 4 ) 1.5 ( Ln =Tb-Er) Phases (Eur. J. Inorg. Chem. 37/2021)
Cover Feature: Spectroscopic Identification of Disordered Molecular Cations in Defect Perovskite-Like A Ln (HCO 2 )(C 2 O 4 ) 1.5 ( Ln =Tb-Er) Phases (Eur. J. Inorg. Chem. 37/2021)
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封面专题：类钙钛矿缺陷 A Ln (HCO 2 )(C 2 O 4 ) 1.5 ( Ln =Tb-Er) 相中无序分子阳离子的光谱鉴定 (Eur. J. Inorg. Chem. 37/2021)
DOI：
10.1002/ejic.202100759
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发表时间：
2021
影响因子：
2.3
通讯作者：
Burley L
中科院分区：
文献类型：
--
作者：
Burley L
封面专题展示了一系列新的 ALn (HCO 2)(C 2 O 4) 1.5 化合物的分析，这些化合物是具有有序阴离子空位和三价镧系元素阳离子的杂化类钙钛矿结构的罕见例子。结合中子和红外光谱，高度无序的 A 位含量被确认为 [(CH 3) 2 NH 2]+ 分子。图片来源：Thomas J. Hitchings（肯特大学）。更多信息可以在 PJ Saines 及其同事撰写的全文中找到。
The Cover Feature shows the analysis of a new series of ALn (HCO 2)(C 2 O 4) 1.5 compounds, which are rare examples of hybrid perovskite-like structures with ordered anion vacancies and trivalent lanthanide cations. The highly disordered A-site contents were confirmed as [(CH 3) 2 NH 2]+ molecules, using a combination of neutron and IR spectroscopy. Image Credit: Thomas J. Hitchings (University of Kent). More information can be found in the Full Paper by PJ Saines and co-workers.