Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules
Synthesis and characterization of π-extended bowl-shaped π-conjugated molecules
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DOI：
10.1039/b701322a
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Hirao, Toshikazu
中科院分区：
文献类型：
--
作者：
Amaya, Toru;Mori, Koichi;Hirao, Toshikazu
以苏曼烯为原料，合成了一系列π延伸的碗状π共轭化合物，并对其结构进行了表征，其中三噻吩衍生物具有明显的吸收峰红移和较小的禁带宽度，并通过分子轨道计算对其进行了合理化.
A series of pi-extended bowl-shaped pi-conjugated compounds were synthesized from sumanene and characterized, and among them the terthiophene derivative showed a remarkable red-shifted absorption and small band gap, which was rationalized by molecular orbital calculation.