High-Valent Co(III)- and Ni(II)-Catalyzed C-H Activation
High-Valent Co(III)- and Ni(II)-Catalyzed C-H Activation
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DOI：
10.1007/s10562-014-1449-4
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发表时间：
2015-01-01
影响因子：
2.8
通讯作者：
Hyster, Todd K.
中科院分区：
文献类型：
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作者：
Hyster, Todd K.
在过去的二十年里，催化C-H活化领域出现了爆炸式增长。虽然这种反应性通常与第二和第三行过渡金属有关，但第一行过渡金属也能够催化这些反应。C-H活化反应可以进一步分为C-H活化与低价金属发生的反应和C-H活化与高价金属发生的反应。本文综述了高价Co（III）和Ni（II）催化C-H活化的研究进展，重点介绍了这些催化剂与第二和第三排同类物的比较。
The past two decades have witnessed explosive growth in the field of catalytic C-H activation. While this reactivity is typically associated with second- and third-row transition metals, first-row transition metals are also capable of catalyzing these reactions. C-H activation reactions can be further divided into ones where the C-H activation occurs with a low-valent metal and those where the activation occurs with a high-valent metal. This review will summarize advances in the area of high-valent Co(III)- and Ni(II)-catalyzed C-H activation with particular emphasis paid to how these catalysts compare their second- and third-row congeners.