Concentration oscillations in the oxidative carbonylation of non-1-yne in the PdI2-KI-CO-O2-CH3OH and PdI2-KI-CO-O2-phenylacetylene-CH3OH systems
Concentration oscillations in the oxidative carbonylation of non-1-yne in the PdI2-KI-CO-O2-CH3OH and PdI2-KI-CO-O2-phenylacetylene-CH3OH systems
复制标题
PdI2-KI-CO-O2-CH3OH 和 PdI2-KI-CO-O2-苯乙炔-CH3OH 体系中非 1-yne 氧化羰基化的浓度振荡
DOI：
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发表时间：
2012
影响因子：
1.1
通讯作者：
S. N. Gorodsky
中科院分区：
文献类型：
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作者：
S. N. Gorodsky
在PdI_2-KI-CO-O_2-CH_3OH体系中，首次观察到壬炔氧化羰基化反应的振荡模式。三乙胺影响该体系中浓度振荡的形成和发展。研究发现，当体系中同时引入另一种炔（苯乙炔）时，非1-炔浓度的振荡特性发生了变化。
The oscillatory mode of the oxidative carbonylation of non-1-yne in the PdI2-KI-CO-O2-CH3OH system has been observed for the first time. Triethylamine affects the formation and development of concentration oscillations in this system. It has been discovered that the character of oscillations of the non-1-yne concentration is changed by the simultaneous introduction of another alkyne (phenylacetylene) into the system.