Organic superconductors: structural aspects and design of new materials

Organic superconductors: structural aspects and design of new materials
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有机超导体:新材料的结构方面和设计

DOI:
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发表时间:
1985
期刊:
影响因子:
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通讯作者:
K. Carlson
K. Carlson
中科院分区:
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文献类型:
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作者:
Jack M. Williams;M. Beno;Hau H. Wang;P. Leung;T. Emge;U. Geiser;K. Carlson

文献摘要

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首次发现常压有机超导体的转变温度高于液氦(4.2K)和第一个超导体金属汞的转变温度。这是金属原子取代I3阴离子中心原子的第一例,有望为合成具有更高转变温度的新型常压有机超导体提供一种新的方法。正如本文所讨论的,有机超导性现在已经在一些硒和S基材料中实现。参考文献76篇,附图6篇。
For the first time, an ambient pressure organic superconductor has been found to have a transition temperature above that both of liquid helium (4.2 K) and the first superconductor, Hg metal. This is the first case of metal atom replacement of the central atom of the I3 anion, and it promises to afford a new means for the synthesis of new ambient pressure organic superconductors with even higher transition temperatures. As discussed in this Account, organic superconductivity has now been realized in a number of Se- and S-based materials. 76 references, 6 figures.