Perfluorocyclobutyl-based methacrylate monomers: Synthesis and radical polymerization
Perfluorocyclobutyl-based methacrylate monomers: Synthesis and radical polymerization
复制标题
全氟环丁基甲基丙烯酸酯单体：合成和自由基聚合
DOI：
10.1016/j.jfluchem.2008.12.012
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发表时间：
2009-03-01
影响因子：
1.9
通讯作者：
Huang, Xiaoyu
中科院分区：
文献类型：
--
作者：
Li, Yongjun;Zhang, Sen;Huang, Xiaoyu
以市售的对取代苯酚、四氟乙烯和甲基丙烯酰氯为原料，经交叉二聚化、去甲基化和酯化反应合成了一类含全氟环丁基单元的新型甲基丙烯酸酯单体。这些单体可以在溶液中聚合得到全氟环丁基聚甲基丙烯酸酯，这是一种潜在的透明材料。(C) 2009 Elsevier B.V.版权所有
A new class of methacrylate monomers containing perfluorocyclobutyl unit was synthesized in multisteps including crossing-dimerization, demethylation and esterification using commercially available p-substituted phenol, tetrafluoroethylene and methacryloyl chloride as starting materials. These monomers can be polymerized in solution to provide perfluorocyclobutyl-based polymethacrylate, a kind of potential transparent material. (C) 2009 Elsevier B.V. All rights reserved.