A Two-Step Fluorescence-Resonance Energy Transfer System Constructed by Platinum(II) Metallacycle Based Molecular Recognition
A Two-Step Fluorescence-Resonance Energy Transfer System Constructed by Platinum(II) Metallacycle Based Molecular Recognition
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DOI：
10.1021/acs.inorgchem.3c02430
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发表时间：
2023-10-10
影响因子：
4.6
通讯作者：
Lin，Qi
中科院分区：
文献类型：
--
作者：
Shi，Bingbing;Qin，Peng;Lin，Qi
在构建高效的荧光共振能量转移(FRET)系统方面取得了长足的进步，促进了人工能量转移材料的发展。然而，尽管最近取得了进展，但探索有效和简单的策略来构建具有FRET活性的新型超分子体系仍然是一个挑战。在这里，我们报告了一个成功的两步FRET系统，由基于铂金属循环的主客体相互作用驱动。两步FRET系统用于制备白光发光二极管，并作为光合作用过程的纳米反应器。这项工作为FRET系统的制造提供了一种策略，并为基于铂(II)金属环的主客体相互作用构建功能材料打开了机会。
Considerable progress in the construction of efficient fluorescence-resonance energy transfer (FRET) systems has promoted the development of artificial energy transfer materials. However, despite recent advances, the exploration of efficient and easy strategies to fabricate novel supramolecular systems with FRET activities is still a challenge. Here, we report that a two-step FRET system was successfully achieved, driven by platinum metallacycle based host–guest interactions. The two-step FRET system is used for the preparation of a white-light-emitting diode and serves as a nanoreactor for the photosynthetic process. This work offers a strategy for the fabrication of FRET systems and opens opportunities for functional materials constructed by platinum(II) metallacycle based host–guest interactions.