Studies in Stereochemistry. V. Phenonium Sulfonate Ion-pairs as Intermediates in the Intramolecular Rearrangements and Solvolysis Reactions that Occur in the 3-Phenyl-2-butanol System
Studies in Stereochemistry. V. Phenonium Sulfonate Ion-pairs as Intermediates in the Intramolecular Rearrangements and Solvolysis Reactions that Occur in the 3-Phenyl-2-butanol System
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立体化学研究。
DOI：
10.1021/ja01129a001
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发表时间：
1952
影响因子：
15
通讯作者：
D. Cram
中科院分区：
文献类型：
--
作者：
D. Cram
Methods The physical properties and anal-yses of the starting materials are re-ported in Table I. The tosylates, brosylates (pbromobenzenesulfo-nates) and acetates as well as the alcohols (IA, IB, IIA and IIB) from which these derivatives were prepared were synthesized by methods that have already been reported. 1 The brosylate of IIA was inordinately unstable, and had to be used as soon as prepared and, when obtained as a product, its properties had to be recorded without delay. Table II records the
