Hyperbranched polymers with controlled degree of branching from 0 to 100%.
Hyperbranched polymers with controlled degree of branching from 0 to 100%.
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DOI：
10.1021/ja105213r
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发表时间：
2010-07
影响因子：
15
通讯作者：
Yukari Segawa;Tomoya Higashihara;M. Ueda
中科院分区：
文献类型：
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作者：
Yukari Segawa;Tomoya Higashihara;M. Ueda
以同一AB(2)单体为原料，采用不同量的三氟甲烷磺酸自缩聚法制备了2,2,2-三氟-1-[4-（4-苯氧苯氧基）苯基]乙酮，成功地合成了线性聚合物、不同支化度的超支化聚合物和100%超支化聚合物。
A linear polymer, hyperbranched polymers with various degrees of branching, and 100% hyperbranched polymers were successfully synthesized by self-polycondensation of 2,2,2-trifluoro-1-[4-(4-phenoxyphenoxy)phenyl]ethanone by using different amounts of trifluoromethanesulfonic acid from the same AB(2) monomer.