A four-step synthesis of the hydroazulene core of guanacastepene

A four-step synthesis of the hydroazulene core of guanacastepene
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DOI:
10.1021/ol016222z
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发表时间:
2001-07-26
期刊:
影响因子:
5.2
通讯作者:
Danishefsky, SJ
Danishefsky, SJ
中科院分区:
化学1区
文献类型:
--
作者:
Dudley, GB;Danishefsky, SJ

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[图表]描述了 2-甲基环戊烯酮向氢甘菊烯 2 的简明四步转化,还讨论了产生意想不到的 [5,5]-双环碳骨架的替代方法。
[GRAPHICS]A concise, four-step conversion of 2-methylcyclopentenone to hydroazulene 2 is described, An alternative approach that led to an unexpected [5,5]-bicyclic carbon framework is also discussed.