Synthetic natural gas from CO hydrogenation over silicon carbide supported nickel catalysts

Synthetic natural gas from CO hydrogenation over silicon carbide supported nickel catalysts
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碳化硅负载镍催化剂上 CO 加氢合成天然气

DOI:
10.1016/j.fuproc.2011.08.002
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发表时间:
2011-12
影响因子:
7.5
通讯作者:
Guo Xiangyun
Guo Xiangyun
中科院分区:
工程技术1区
文献类型:
--
作者:
Yu Yue;Jin Guoqiang;Wang Yingyong;Guo Xiangyun

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采用浸渍法制备了碳化硅负载镍CO甲烷化催化剂。在没有稀释气体的情况下,在固定床反应器中用H2/CO=3流测试催化剂的活性。结果表明,在550℃下煅烧的15wt.% Ni/SiC催化剂表现出优异的催化活性。与15wt.% Ni/TiO2催化剂相比,Ni/SiC催化剂在甲烷化反应中表现出更高的活性和稳定性。 X射线衍射和透射电子显微镜的表征结果表明,由于SiC优异的热稳定性和高导热性,Ni/SiC催化剂没有发生明显的催化剂烧结。
Silicon carbide supported nickel catalysts for CO methanation were prepared by impregnation method. The activity of the catalysts was tested in a fixed-bed reactor with a stream of H2/CO=3 without diluent gas. The results show that 15wt.% Ni/SiC catalyst calcined at 550°C exhibits excellent catalytic activity. As compared with 15wt.% Ni/TiO2catalyst, the Ni/SiC catalyst shows higher activity and stability in the methanation reaction. The characterization results from X-ray diffraction and transmission electron microscopy suggest that no obvious catalyst sintering has occurred in the Ni/SiC catalyst due to the excellent thermal stability and high heat conductivity of SiC.
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