Robust metal-organic framework enforced by triple-framework interpenetration exhibiting high H2 storage density.
Robust metal-organic framework enforced by triple-framework interpenetration exhibiting high H2 storage density.
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DOI：
10.1021/ic800854y
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发表时间：
2008-06
影响因子：
4.6
通讯作者：
Ming Xue;Shengqian Ma;Zhao Jin;Roxanna M. Schaffino;G. Zhu;E. Lobkovsky;S. Qiu;Banglin Chen
中科院分区：
文献类型：
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作者：
Ming Xue;Shengqian Ma;Zhao Jin;Roxanna M. Schaffino;G. Zhu;E. Lobkovsky;S. Qiu;Banglin Chen
微孔金属有机骨架 1 Zn 2(CNC) 2(DPT).G [CNC = 4-Carboxycinnamic; DPT = 3,6-二-4-吡啶基-1,2,4,5-四嗪； G =客体分子]是通过具有约3.7 A的一维孔的三重互穿原始立方网合成和结构表征的。1通过弱范德华相互作用通过三重骨架互穿而增强，因此活化的1b吸收1.28 wt%的氢气，并在1 atm和77 K下表现出95.2%的高储氢密度。
A microporous metal-organic framework 1 Zn 2(CNC) 2(DPT).G [CNC = 4-Carboxycinnamic; DPT = 3,6-Di-4-pyridyl-1,2,4,5-tetrazine; G = guest molecules] was synthesized and structurally characterized by a triply interpenetrated primitive cubic net with 1D pores of about 3.7 A. 1 is highly robust enforced by triple framework interpenetration through weak van der Waals interactions, thus the activated 1b takes up 1.28 wt % hydrogen gas and exhibits high hydrogen storage density of 95.2% at 1 atm and 77 K.