SYNTHESIS OF 1,1'-DIBENZYL-5,5'-7,7'-BIS(HEXANO)BIS[6(1H)-CYCLOHEPTATRIAZOLONE], A NOVEL HETEROCYCLIC RING-SYSTEM
SYNTHESIS OF 1,1'-DIBENZYL-5,5'-7,7'-BIS(HEXANO)BIS[6(1H)-CYCLOHEPTATRIAZOLONE], A NOVEL HETEROCYCLIC RING-SYSTEM
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DOI：
10.1021/je00046a037
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发表时间：
1986-10-01
期刊：
影响因子：
--
通讯作者：
HARMON, RE
中科院分区：
文献类型：
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作者：
ABUORABI, ST;HARMON, RE
我们对三唑衍生物的合成和反应的持续兴趣(1)使我们制备了新的环状体系，1,1 '-二苯基- 5,5 ':7,7 '-双（己）双[6 (1H)-环庚三唑酮]，以研究聚亚甲基桥对在同一分子内含有两个三唑酮体系的体系的芳香性和平面性的影响（2,3）。质子H4和H8的Me4Si发生了7.70 ppm的核磁共振化学位移，这是由于三唑戊酮体系平面度的增加和环电流的存在，从而得出该化合物在环环部分是芳香的结论。
Our continuing interest in the syntheses and reactions of triazole derivatives (1) has led us to prepare the novel ring system, 1, 1'-dibenzyl-5, 5': 7, 7'-bis (hexano) bis [6 (1H)-cycloheptatriazolone] in order to study the effect of the polymethylene bridge on the aromaticity and planarity of a system which contains two triazoletropone systems within the same molecule (2, 3). The observed NMR chemical shift of 7.70 ppm from Me4Si of the protons H4 and H8 can be attributed to an increase in the planarity of the triazoletropone system and also to the existence of a ring current which leads to the conclusion that this compound is aromatic in the tropone ring portion.