Oligo- and Polythiophene/ZnO Hybrid Nanowire Solar Cells

Oligo- and Polythiophene/ZnO Hybrid Nanowire Solar Cells
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DOI:
10.1021/nl9036752
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发表时间:
2010-01-01
期刊:
影响因子:
10.8
通讯作者:
Yang, Peidong
Yang, Peidong
中科院分区:
材料科学1区
文献类型:
--
作者:
Briseno, Alejandro L.;Holcombe, Thomas W.;Yang, Peidong

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我们演示了有机/无机混合单纳米线太阳能电池的基本操作。将末端官能化的寡聚噻吩和聚噻吩接枝到ZnO纳米线上以产生。p-n异质结纳米线。通过吸收和电子显微镜的混合纳米结构的特征在于,以确定光电性能和探测在有机/无机界面的形态。单个纳米线太阳能电池器件在AM 1.5照明和100 mW/cm(2)光强度下表现出良好的分辨特性,效率高达0.036%,J(sc)= 0.32 mA/cm(2),V-oc = 0.4 V,FF = 0.28。这些单独的测试结构将使详细的分析,已难以研究在体异质结器件的领域进行。
We demonstrate the basic operation of an organic/inorganic hybrid single nanowire solar cell. End-functionalized oligo- and polythiophenes were grafted onto ZnO nanowires to produce. p-n heterojunction nanowires. The hybrid nanostructures were characterized via absorption and electron microscopy to determine the optoelectronic properties and to probe the morphology at the organic/inorganic interface. Individual nanowire solar cell devices exhibited well-resolved characteristics with efficiencies as high as 0.036%, J(sc) = 0.32 mA/cm(2), V-oc = 0.4 V, and a FF = 0.28 under AM 1.5 illumination with 100 mW/cm(2) light intensity. These individual test structures will enable detailed analysis to be carried Out in areas that have been difficult to study in bulk heterojunction devices.