Design and synthesis of tetranuclear cluster monophosphine-cyclopalladated ferrocenylpyrimidinone complexes from the palladium-catalyzed hydroxylation of chloropyrimidine
Design and synthesis of tetranuclear cluster monophosphine-cyclopalladated ferrocenylpyrimidinone complexes from the palladium-catalyzed hydroxylation of chloropyrimidine
复制标题
钯催化氯嘧啶羟基化反应设计和合成四核簇单膦-环钯二茂铁基嘧啶酮配合物
DOI：
10.1039/c0cc01870h
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发表时间：
2010-01-01
影响因子：
4.9
通讯作者：
Ji, Bao-Ming
中科院分区：
文献类型：
--
作者：
Xu, Chen;Zhang, Ya-Peng;Ji, Bao-Ming
单体三苯基膦-环钯二茂铁氯嘧啶[PdCl{[(eta(5)-C(5)H(5))]Fe[(eta(5)-C(5)H(3))-N(2)-C(4)H(2)-Cl]}(PPh(3))]与KOH的羟基化反应首次得到了四核簇状单膦-聚吡啶环[Pd{[(eta(5)-C(5)H(5))]Fe[(eta(5)-C(5)H(3))]-N(2)C(4)H(2)O]}(PPh(3))](4)。此外，用同样的方法还成功地合成了类似的三环己基膦四核簇合物。
Hydroxylation of a monomeric triphenylphosphine-cyclopalladated ferrocenylchloropyrimidine [PdCl{[(eta(5)-C(5)H(5))]Fe[(eta(5)-C(5)H(3))-N(2)-C(4)H(2)-Cl]}(PPh(3))] with KOH gave the first example of a tetranuclear cluster monophosphine-palladacycle [Pd{[(eta(5)-C(5)H(5))]Fe[(eta(5)-C(5)H(3))-N(2)C(4)H(2)O]}(PPh(3))](4). Additionally, the analogous tricyclohexylphosphine tetranuclear cluster palladacycle has also been successfully synthesized by the same method.