Stable singlet carbenes as mimics for transition metal centers.
Stable singlet carbenes as mimics for transition metal centers.
复制标题
DOI：
10.1039/c0sc00388c
复制
发表时间：
2011-01-01
期刊：
影响因子：
8.4
通讯作者：
Bertrand G
中科院分区：
文献类型：
--
作者：
Martin D;Soleilhavoup M;Bertrand G
这一观点总结了最近的结果，这些结果表明，稳定的卡宾可以激活小分子(CO、H2、NH3和P4)，并稳定高活性的中间体(主要族元素处于零氧化态和顺磁性物种)。这两项任务以前是过渡金属络合物所独有的。
This perspective summarizes recent results, which demonstrate that stable carbenes can activate small molecules (CO, H2, NH3 and P4) and stabilize highly reactive intermediates (main group elements in the zero oxidation state and paramagnetic species). These two tasks were previously exclusive for transition metal complexes.